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potassium bifluoride : ウィキペディア英語版
potassium bifluoride

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Potassium bifluoride is the inorganic compound with the formula KHF2. This colourless salt consists of the potassium cation and the bifluoride (HF2) anion. The salt is used in etchant for glass. Sodium bifluoride is related and is also of commercial use as an etchant as well as in cleaning products.〔Jean Aigueperse, Paul Mollard, Didier Devilliers, Marius Chemla, Robert Faron, Renée Romano, Jean Pierre Cuer, “Fluorine Compounds, Inorganic” in Ullmann’s Encyclopedia of Industrial Chemistry 2005 Wiley-VCH, Weinheim. 〕
==Nature of the chemical bond in the bifluoride anion==
Potassium bifluoride, as its name indicates, contains a bifluoride, or hydrogen(difluoride) anion: HF2. This centrosymmetric triatomic anion features the strongest known hydrogen bond, with a FH length of 114 pm, and a bond energy greater than 155 kJ mol−1.〔Emsley, J. (1980) ''Very strong hydrogen bonds'', Chemical Society Reviews, 9, 91-124.〕

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